Influence of the chemical structure of terminal groups on the properties of ultrafiltration membranes from polyphenylene sulphone

Capa

Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Somente assinantes

Resumo

For the first time, for the problem of high-performance ultrafiltration flat-sheet membranes casting, polyphenylene sulfones (PPSF) with chlorine and hydroxyl terminal groups were synthesized and studied. The synthesis of PPSF was carried out in dimethylacetamide at different ratios of 4,4′-dihydroxydiphenyl and 4,4-dichlorodiphenylsulfone monomers. Two samples with a predominant content of hydroxyl and chlorine terminal groups, PPSF-OH and PPSF-Cl, were studied using NMR, GPC and DSC methods. The coagulation values of polymer solutions in N-methyl-2-pyrrolidone (NMP), the mechanical properties and hydrophilicity of the materials were also determined. Both PPSF samples have high strength modulus (16.0–16.6 MPa). Using the method of deposition in water of PPSF solutions in NMP with PEG-400 additives, flat-sheet porous asymmetric m embranes with a mesoporous (diameter of about 7 nm) thin outer layer and finger-like macropores in the substrate were obtained. An increase in the proportion of –OH terminal groups increases the hydrophilicity of the polymer. This, in turn, made it possible to obtain flat-sheet membranes based on PPSF-OH with a water permeability of 66.1 l/m2 h bar, which is 1.5 times higher than the water permeability of the PFSF-Cl membrane. At the same time, both membranes demonstrate the Blue Dextran (Mw = 70,000 g mol–1) rejection of 99.9%.

Sobre autores

D. Matveev

Kabardino-Balkarian State University named after H.M. Berbekov

Autor responsável pela correspondência
Email: dmatveev@ips.ac.ru
Rússia, Chernyshevsky str., 173, Nalchik, 360004

А. Raeva

Kabardino-Balkarian State University named after H.M. Berbekov

Email: dmatveev@ips.ac.ru
Rússia, Chernyshevsky str., 173, Nalchik, 360004

A. Zhansitov

Kabardino-Balkarian State University named after H.M. Berbekov

Email: dmatveev@ips.ac.ru
Rússia, Chernyshevsky str., 173, Nalchik, 360004

K. Shakhmurzova

Kabardino-Balkarian State University named after H.M. Berbekov

Email: dmatveev@ips.ac.ru
Rússia, Chernyshevsky str., 173, Nalchik, 360004

Zh. Kurdanova

Kabardino-Balkarian State University named after H.M. Berbekov

Email: dmatveev@ips.ac.ru
Rússia, Chernyshevsky str., 173, Nalchik, 360004

Т. Anokhina

Topchiev Institute of Petrochemical Synthesis, RAS

Email: dmatveev@ips.ac.ru
Rússia, Leninsky prospect, 29, Moscow, 119991

S. Khashirova

Kabardino-Balkarian State University named after H.M. Berbekov

Email: dmatveev@ips.ac.ru
Rússia, Chernyshevsky str., 173, Nalchik, 360004

V. Volkov

Kabardino-Balkarian State University named after H.M. Berbekov

Email: dmatveev@ips.ac.ru
Rússia, Chernyshevsky str., 173, Nalchik, 360004

I. Borisov

Kabardino-Balkarian State University named after H.M. Berbekov

Email: dmatveev@ips.ac.ru
Rússia, Chernyshevsky str., 173, Nalchik, 360004

Bibliografia

  1. Praneet, K., James T., Sridha, S. // Chemical Engineering Journal. 2014. V. 248. P. 297-306.
  2. Darvishmanesh S., Jansen J.C., Tasselli F., Tocci E., Luis P., Degreve J., Drioli E1., Van der Bruggen B. // Journal of Membrane Science. 2011. V. 379. № 1–2. P. 60–68.
  3. Darvishmanesh S., Tasselli F., Jansen J. C., Tocci E., Bazzarelli F., Bernardo P., Luis P., Degreve J., Drioli E., Van der Bruggen B. // Journal of membrane science. 2011. V. 384. № 1–2. P. 89–96.
  4. Dizman C., Tasdelen M. A., Yagci Y. // Polymer International. 2013. V. 62. № 7. P. 991–1007.
  5. Ultrason® E, S, P (PESU, PSU, PPSU). URL: https://www.basf.com/cn/documents/en/chinaplas/UltrasonESPproductbrochureEN.pdf (Дата обращения: 27.10.2023).
  6. Nayak M. C., Isloor A. M., Moslehyani A., Ismail A.F. // Journal of the Taiwan Institute of Chemical engineers. 2017. V. 77. P. 293–301.
  7. Kiani S., Mousavi S. M., Shahtahmassebi N., Saljoughi E. // Desalination and Water Treatment. 2016. V. 57. №. 35. P. 16250–16259.
  8. Feng Y., Han G., Zhang L., Chen S. B., Chung T. S., Weber M., Staudt C., Maletzko C. // Polymer. 2016. V. 99. P. 72–82.
  9. Xiao S., Yu S., Yan L., Liu Y., Tan X. // Chinese Journal of Chemical Engineering. V. 25. № 4. P. 408–414.
  10. Hwang L. L., Chen J. C., Wey M. Y. // Desalination. 2013. V. 313. P. 166-175.
  11. Gronwald O., Frost I., Ulbricht M., KouchakiShalmani A., Panglisch S., Grünig L., Handge U., Abetz V., Heijnen M., Weber M. // Separation and Purification Technology. 2020. V. 250. P. 117107–117127.
  12. Moideen K, I., Isloor A.M., Ismail A.F., Obaid A., Fun H.K. // Desalination and Water Treatment. 2016. V. 57. № 42. P. 19810–19819.
  13. Yin Q., Zhang Q., Cui Z., Li W., Xing W. // Polymer. 2017. V. 124. P. 128–138.
  14. Arockiasamy D.L., Alhoshan M., Alam J., Muthumareeswaran M.R., Figoli A., Kumar S.A. // Separation and Purification Technology. 2017. V. 174. P. 529–543.
  15. Tang Y., Widjojo N., Shi G. M., Chung T. S., Weber M., Maletzko C. // Journal of membrane science. 2012. V. 415. P. 686-695.
  16. Jullok N., Van Hooghten R., Luis P., Volodin A., Van Haesendonck C., Vermant J., Van der Bruggen B. // Journal of Cleaner Production. 2016. V. 112. P. 4879–4889.
  17. Jullok N., Darvishmanesh S., Luis P., Van der Bruggen B. // Chemical engineering journal. 2011. V. 175. P. 306–315.
  18. Jullok N., Deforche T., Luis P., Van der Bruggen B. // Chemical engineering science. 2012. V. 78. P. 14–20.
  19. Fritzsche A.K., Murphy M.K., Cruse C.A., Malon R.F., Kesting R.E. // Gas Separation & Purification. 1989. V. 3. № 3. P. 106–116.
  20. Weng T. H., Tseng H. H., Wey M. Y. // International journal of hydrogen energy. 2008. V. 33. № 15. P. 4178–4182.
  21. Sani N. A. A., Lau W. J., Ismail A. F. // RSC Advances. 2015. V. 5. № 17. P. 13000–13010.
  22. Sani N. A. A., Lau W. J., Ismail A. F. // Journal of Polymer Engineering. 2014. V. 34. № 6. P. 489–500.
  23. Alsalhy Q. F., Ali J. M., Abbas A. A., Rashed A., Bruggen B. V. D., Balta S. // Desalination and Water Treatment. 2013. V. 51. № 31–33. P. 6070–6081.
  24. Luo L., Han G., Chung T. S., Weber M., Staudt C., Maletzko C. // Journal of Membrane Science. 2015. V. 476. P. 162–170.
  25. Plisko T., Karslyan Y., Bildyukevich A. // Materials. 2021. V. 14. № 19. P. 5740.
  26. Anokhina T., Raeva A., Sokolov S., Storchun A., Filatova M., Zhansitov A., Kurdanova Z., Shakhmurzova K.,Khashirova S., Borisov I. // Membranes. 2022. V. 12. №. 11 P. 1113.
  27. Борисов И.Л., Матвеев Д.Н., Анохина Т.С., Шахмурзова К.Т., Жанситов А.А., Слонов А.Л., Курданова Ж.И., Хаширова С.Ю., Волков В.В. // Мембраныимембранныетехнологии. 2023. Т. 13. № 3. С. 248–256.
  28. Matveev D., Raeva A., Borisov I., Vasilevsky V., Matveeva Y., Zhansitov A., Khashirova S., Volkov V. // Membranes. 2023. V. 13. № 4. P. 412.

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML
Baixar

Declaração de direitos autorais © Russian Academy of Sciences, 2024