The effect of a magnetic field on the generation of free radicals in the interaction of quaternary ammonium compounds with hydroperoxides

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Resumo

The magnetic effects (ME) of a moderate magnetic field (MF, 600 mT) on the rate of radical generation (Wi) in mixed micellar systems of quaternary ammonium compounds with hydroperoxides (QAC-ROOH), measured by the inhibitor method, and the effect of magnetic field on the rate of radical polymerization initiated by radicals, generated from the surface by QAC chemisorbed on a solid carrier upon interaction with hydroperoxide dissolved in the monomer are compared. It has been established that in micellar solutions MF reduces Wi, ME ≈ –0.45. In the case of radical polymerization of styrene containing cumyl hydroperoxide on the surface of mica plates with a chemisorbed monolayer of QAC (CTAB or ACh), the polymerization rate increases in MF.

Sobre autores

D. Krugovov

Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Autor responsável pela correspondência
Email: kagur1982@mail.ru
Rússia, Moscow

A. Gatin

Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: kagur1982@mail.ru
Rússia, Moscow

N. Potapova

Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: kagur1982@mail.ru
Rússia, Moscow

V. Kondratovich

Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: kagur1982@mail.ru
Rússia, Moscow

E. Mengele

Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: kagur1982@mail.ru
Rússia, Moscow

O. Kasaikina

Semenov Federal Research Center for Chemical Physics of the Russian Academy of Sciences

Email: kagur1982@mail.ru
Rússia, Moscow

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