Influence of self-heating on the kinetics of an exothermal reaction under isothermal conditions

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Аннотация

Estimates have been made showing that when an exothermal reaction proceeds in an isothermal medium (in a thermostat), self-heating occurs, the values of which are determined by the competition between the processes of heat input and heat removal. Relationships are obtained that make it possible to estimate the deviation of the observed values of the kinetic parameters from the true values and to reveal the influence of various parameters on these deviations.

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Авторлар туралы

B. Korsunskiy

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry
Russian Academy of Sciences; N.N. Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences

Email: n.g.samoilenko@mail.ru
Ресей, Chernogolovka; Moscow

N. Samoilenko

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry
Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: n.g.samoilenko@mail.ru
Ресей, Chernogolovka

Әдебиет тізімі

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  3. A. I. Serbinov, Zhurnal fiz. khimii 33(12), 2641 (1970) (in Russian).
  4. D. A. Frank-Kamenetskii, Diffusion and Heat Exchange in Chemical Kinetics (Nauka, Moscow, 1987; Springer, Heidelberg, 1995).
  5. R. Meyer, J. Kohler, A. Homburg, Explosives. (Wiley-VCH, 2002. 474 p.).
  6. G. B. Manelis, G. M. Nazin, Yu.I. Rubtsov, V.A. Strunin. Thermal Decomposition and Combustion of Explosives and Propellants G. B. Manelis, s. (Taylor and Francis Croup. L.-N.Y. 2003. 362 p.)
  7. S. S. Kutateladze, V. M. Borishanskiy. Spravochnik po teploperedache. (Gosudarstvennoye izdatel’stvo energeticheskoy literatury. L.-М. 1958. 414 p.) (in Russian).

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