Energy capabilities of model mixed solid propellants based on dinitrobifuroxans, dinitrotrifuroxans and dinitroazobifuroxans

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Abstract

The energy capabilities of some dinitrobifuroxans, dinitrotrifuroxans and dinitroazоbifuroxans as potential components of mixed solid propellants have been studied. The effect of isomerism of these compounds on the energy capabilities of model compositions based on them is considered. For this purpose, thermodynamic calculations were carried out for six compounds with nitrobifuroxan fragments in the molecules. Quantitative dependences of the energy parameters of the fuel on the properties of the oxidizer under study, the type of binder and the content of the latter have been established. For this purpose, thermodynamic calculations were carried out for six compounds with nitrobifuroxan fragments in the molecules.

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About the authors

I. N. Zyuzin

Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Author for correspondence.
Email: zyuzin@icp.ac.ru
Russian Federation, Chernogolovka

I. Yu. Gudkova

Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: zyuzin@icp.ac.ru
Russian Federation, Chernogolovka

D. B. Lempert

Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: zyuzin@icp.ac.ru
Russian Federation, Chernogolovka

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2. Fig.1. Structural formulas of compounds I–VI: I – 3,4′-dinitro-3,3′-bifuroxan; II – 4,3′-dinitro-3,4′-bifuroxane; III – 3,4-bis(4-nitro-furoxan-3-yl)furoxan; IV – 3,4-bis(4-nitro-furoxan-3-yl)furoxan; V – 4,4′-di(4-nitrofuroxan-3-yl)-3,3′-azofuroxan; VI – 4,4′-di(3-nitrofuroxan-4-yl)-3,3′-azofuroxan.

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3. Fig. 2. Dependence of the value of Ief(3) of the composition “AC + US + main filler I–VII” on the proportion of US in the total binder “AC + US” with a volume content of binder of 18%.

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4. Scheme

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