Energy capabilities of some pentazole salts as components of model composite solid propellants

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Abstract

The energy capabilities of five pentazole salts as fillers for composite solid propellants (СSP) were studied. Of these, only hydroxylammonium pentazolate (IV) turned out to be a relatively good component for creating model СSPs. Compound IV is superior to HMX in terms of Ief(3) both in a binary composition with an active binder and in similar compositions with the addition of AP, ADN or Al. Lithium, ammonium, hydrazinium and 1,4,5-triaminotetrazolium pentazolates are inferior to HMX as the main filler for CSP.

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About the authors

I. N. Zyuzin

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian academy of sciences

Author for correspondence.
Email: zyuzin@icp.ac.ru
Russian Federation, Chernogolovka

I. Y. Gudkova

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian academy of sciences

Email: zyuzin@icp.ac.ru
Russian Federation, Chernogolovka

D. B. Lempert

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian academy of sciences

Email: zyuzin@icp.ac.ru
Russian Federation, Chernogolovka

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2. Fig. 1. Structural formulas of pentazolates I–V: I — lithium; II — ammonium; III — hydrazinium; IV — hydroxylammonium; V — 1,4,5-triaminotetrazolium.

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3. Fig. 2. Dependence of the value of Ief(3) of the compositions “compounds I–V or HMX + AC + PHA” on the proportion of PHA in the mixed filler with a volume content of the active binder of 18%.

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4. Fig. 3. Dependence of the value of Ief(3) of the compositions “compounds I–V or HMX + AC + ADNA” on the proportion of ADNA in the mixed filler with a volume content of the active binder of 18%.

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5. Fig. 4. Dependence of I *ef(3) of the “compounds I–V or HMX + Al” compositions on the proportion of Al in the mixed filler with a volume content of the active binder of 18%.

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