Influence of an Ultralow Graphene Content on the Physical and Mechanical Characteristics of Uhmwpe-Based Composites

Cover Page

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

The polymerization filling method is used to obtain nanocomposites based on ultrahigh molecular
weight polyethylene (UHMWPE) and graphene at with an ultralow content of 0.0065–0.019 vol %. The
melting points and degrees of crystallinity of the obtained composites are close to the corresponding characteristics
of unfilled UHMWPE. The strain-strength properties under the tension of the samples of the
obtained composites are studied depending on the content of graphene. It is shown that the tensile strength
of the composites increases significantly with an increase in the graphene content to 0.012 vol % compared
to unfilled UHMWPE with a subsequent decrease. The relative elongation changes in a similar way.

About the authors

A. S. Zabolotnov

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: zabolotnov.ru@gmail.com
Moscow, Russia

S. S. Gostev

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: zabolotnov.ru@gmail.com
Moscow, Russia

I. A. Maklakova

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: zabolotnov.ru@gmail.com
Moscow, Russia

L. A. Novokshonova

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: zabolotnov.ru@gmail.com
Moscow, Russia

V. G. Krasheninnikov

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Email: zabolotnov.ru@gmail.com
Moscow, Russia

M. V. Gudkov

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Author for correspondence.
Email: zabolotnov.ru@gmail.com
Moscow, Russia

References

  1. Steven M.K. UHMWPE Biomaterials Handbook, 2nd edn. B.: Academic Press, 2009.
  2. Majid Md., Khan M.S., Dr. Moeed K.M., Fatima Z. // Intern. J. Eng. Trends and Appl. 2016. V. 3. P. 26.
  3. Wen J., Yin P., Zhen M. // Mater. Lett. 2008. V. 62. № 25. P. 4161; https://doi.org/10.1016/j.matlet.2008.06.003
  4. Гоголева О.В., Петрова П.Н., Попов С.Н., Охлопкова А.А. // Трение и износ. 2015. Т. 36. № 4. С. 394; https://doi.org/10.3103/S1068366615040054
  5. Панин C.В., Панин В.Е., Корниенко Л.А. и др. // Химия и хим. технол. 2011. Т. 54. № 7. С. 102.
  6. Селютин Г.Е., Гаврилов Ю.Ю., Воскресенская Е.Н. и др. // Химия в интересах устойч. развит. 2010. Т. 18. № 3. С. 375.
  7. Новокшонова Л.А., Мешкова И.Н. // Высокомолекуляр. соединения. 1994. Т. 36. № 4. С. 629.
  8. Бревнов П.Н., Кирсанкина Г.Р., Заболотнов А.С. и др. // Высокомолекуляр. соединения. С. 2016. Т. 58. № 1. С. 42; https://doi.org/10.7868/S2308114716010027
  9. Chmutin I., Novokshonova L., Brevnov P., Yukhayeva G., Ryvkina N. // Polyolef. J. 2017. V. 4. № 1. P. 1; https://doi.org/10.22063/POJ.2016.1384
  10. Заболотнов А.С., Бревнов П.Н., Акульшин В.В. и др. // Все материалы. Энциклопед. справ. 2017. № 12. С. 13.
  11. Xiong D.S., Lin J.M., Fan D.L. // Biomed. Mater. 2006. V. 1. P. 175.
  12. Xiong D., Lin J., Fan D., Jin Z. // J. Mater. Sci. 2007. V. 18. P. 2131.
  13. Kudinova O.I., Nezhnyi P.A., Grinev V.G. et al. // J. Phys. Chem. B. 2022. V. 16. № 4. P. 764; https://doi.org/10.1134/S199079312204025
  14. Бревнов П.Н., Заболотнов А.С., Крашенинников В.Г. и др. // Кинетика и катализ. 2016. Т. 57. № 4. С. 484; https://doi.org/10.7868/S0453881116030011
  15. Zhang H., Moon Y.K., Zhang X.Q. et al. // Eur. Polym. J. 2017. V. 87. P. 60; https://doi.org/10.1016/j.eurpolymj.2016.12.010
  16. Wannasri S., Panin S.V., Ivanova L.R., Kornienko L.A., Piriyayon S. // Proced. Eng. 2009. V. 1. P. 67; https://doi.org/10.1016/j.proeng.2009.06.018
  17. Ren X., Wang X.Q., Sui G. et al. // J. Appl. Polym. Sci. 2008. V. 107. № 5. P. 2837; https://doi.org/10.1002/app.27354
  18. Wood W.J., Maguire R.G., Zhong W.H. // Composites Part B. 2011. V. 42. № 3. P. 584; https://doi.org/10.1016/j.compositesb.2010.09.006
  19. Puertolas J.A., Martinez-Nogues V., Martinez-Morlanes M.J. et al. // Wear. 2010. V. 269. № 5–6. P. 458; https://doi.org/10.1016/j.wear.2010.04.033
  20. Polschikov S.V., Nedorezova P.M., Palaznik O.M. et al. // Polym. Eng. Sci. 2018. V. 58. № 9. P. 1461; https://doi.org/10.1002/pen.24644
  21. Samad M.A., Sinha S.K. // Tribol. Intern. 2011. V. 44. № 12. P. 1932; https://doi.org/10.1016/j.triboint.2011.08.001
  22. Hyunwoo K., Abdala A.A., Christopher W.M. // Macromol. 2010. V. 43. № 16. P. 6515; https://doi.org/10.1021/ma100572e
  23. Lee C., Wei X., Kysar J.W., Hone J. // Science. 2008. V. 321. P. 385; https://doi.org/10.1126/science.1157996
  24. Ansón-Casaos A., Puértolas J.A. // Tribol. Intern. 2017. V. 116. P. 1; https://doi.org/10.1016/j.triboint.2017.06.039
  25. Jing T., Yihui W., Weimin C., Jiayuan Y., Ping X. // Polym. Test. 2021. V. 99. P. 1; https://doi.org/10.1016/j.polymertesting.2021.107217
  26. Ушакова Т.М., Старчак Е.Е., Гостев С.С. и др. // Хим. физика. 2020. Т. 39. № 5. С. 66; https://doi.org/10.31857/S0207401X2005012X
  27. Гоголева О.В., Петрова П.Н., Попов С.Н., Охлопкова А.А. // Трение и износ. 2015. Т. 36. № 4. С. 394.
  28. Chih A., Anson-Casaos A., Puertolas J.A. // Tribol Intern. 2017. V. 116. P. 295; https://doi.org/10.1016/j.triboint.2017.07.027
  29. Tai Z., Chen Y., An Y., Yan X., Xue Q. // Ibid. 2012. V. 46. P. 55; https://doi.org/10.1007/s11249-012-9919-6
  30. Lahiri D., Hec F., Thiesse M. et al. // Ibid. 2014. V. 70. P. 165; https://doi.org/10.1016/j.triboint.2013.10.012
  31. Ozerin A.N., Kechek’yan A.S., Golubev E.K. et al. // Nanotech. in Russia. 2015. V. 10. № 1–2. P. 42; https://doi.org/10.1134/S1995078015010115
  32. Shiyanova K.A, Gudkov M.V., Gorenberg A.Y. et al. // ACS Omega. 2020. № 5. V. 39. P. 25148; https://doi.org/10.1021/acsomega.0c02859
  33. Pei S., Cheng H.M. // Carbon. 2012. V. 50. № 9. P. 3210; https://doi.org/10.1016/j.carbon.2011.11.010
  34. Аладышев А.М., Клямкина А.Н., Недорезова П.М., Киселева Е.В. // Хим. физика. 2020. Т. 39. № 7. С. 56; https://doi.org/10.31857/S0207401X2007002X
  35. Перова А.Н., Бревнов П.Н., Усачев С.В. и др. // Хим. физика. 2021. Т. 40. № 7. С. 49; https://doi.org/10.31857/S0207401X21070074

Supplementary files

Supplementary Files
Action
1. JATS XML
2.

Download (26KB)
3.

Download (26KB)
4.

Download (29KB)

Copyright (c) 2023 А.С. Заболотнов, С.С. Гостев, И.А. Маклакова, Л.А. Новокшонова, В.Г. Крашенинников, М.В. Гудков