Dependence of the TNT equivalent of an underwater explosion on the content of aluminum hydride in the energy material

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Abstract

The results obtained show that the addition of aluminum (Al) and aluminum hydride (AlH3) to the explosive significantly increases the heat of explosion and the TNT equivalent (TE) of an underwater explosion. The compositions with AlH3 are inferior to the Al-containing counterparts in the heat of explosion. However, the formulations with AlH3 have the advantage in terms of the number of moles of gaseous products. Replacing Al with AlH3 weakly affects the TE in terms of the energy of gas bubble, while the TE in terms of the energy of shock wave is higher for the mixtures with AlH3. The latter is especially noticeable in the case of the explosive with a positive oxygen balance. However, the compositions with AlH3 are inferior to the Al-containing mixtures in the volumetric TE.

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About the authors

M. N. Makhov

Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences

Author for correspondence.
Email: mmn13makhov@yandex.ru
Russian Federation, Moscow

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Supplementary files

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2. Fig. 1. Heat of explosion (Q) and the number of moles of gaseous explosion products (N) depending on β mass fraction of Al (solid lines) and AlH3 (dashed lines) in a mixture with octogen. Symbols are experimental values ​​of the heat of explosion of aluminum-containing compositions.

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3. Fig. 2. Same as in Fig. 1, but for a composition with the substance BTNEN.

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4. Fig. 3. Dependence of the TNT equivalent in shock wave energy on the mass fraction of Al (solid lines) and AlH3 (dashed lines) in a mixture with BTNEN (1) and HMX (2).

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5. Fig. 4. Dependence of the volumetric TNT equivalent in shock wave energy on the mass fraction of the additive. The designations are the same as in Fig. 3

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