Lithium-Conducting Nafion Membrane Plasticized with a DMSO–Sulfolane Mixture

R. R. Kayumov; Каюмов Р. Р.; A. P. Radaeva; Радаева А. П.; A. A. Krupina; Крупина А. А.; K. A. Tarusina; Тарусина К. А.; A. N. Lapshin; Лапшин А. Н.; L. V. Shmygleva; Шмыглева Л. В.

doi:10.31857/S0207401X23070099

Lithium-Conducting Nafion Membrane Plasticized with a DMSO–Sulfolane Mixture

Authors: Kayumov R.R.¹, Radaeva A.P.¹, Krupina A.A.¹^,2, Tarusina K.A.¹, Lapshin A.N.¹, Shmygleva L.V.¹
Affiliations:
1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
2. Moscow Institute of Physics and Technology
Issue: Vol 42, No 7 (2023)
Pages: 23-32
Section: XXXIV СИМПОЗИУМ “СОВРЕМЕННАЯ ХИМИЧЕСКАЯ ФИЗИКА” (СЕНТЯБРЬ 2022 г., ТУАПСЕ)
URL: https://vestnikugrasu.org/0207-401X/article/view/674849
DOI: https://doi.org/10.31857/S0207401X23070099
EDN: https://elibrary.ru/YCALKG
ID: 674849

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

The effect of the composition of a binary plasticizing mixture based on dimethyl sulfoxide and sulfolane on the physicochemical properties of the lithium form of the Nafion membrane is studied. To explain the behavior of the electrotransport properties of membranes, experimental studies of intermolecular interactions, thermal behavior, and the ion-transport properties of the obtained lithium-conducting polyelectrolytes are carried out using IR spectroscopy, simultaneous thermal analysis, and impedance spectroscopy. A relationship is found between the shift of the eutectic point to the region of a lower content of sulfolane compared to bulk solvents and the composition of the plasticizer, in which the samples had the best conductivity of 0.76 mS/cm at 30°C.

Keywords

polyelectrolyte, Nafion-Li, aprotic solvent, IR spectroscopy, simultaneous thermal analysis, ionic conductivity

References

Fan X., Wang C. // Chem. Soc. Rev. 2021. V. 50. P. 10 486.
Gibbs H.H., Griffin R.N. // Patent 3041317A US. 1962.
Connolly D.J., Gresham W.F. // Patent 3282875 US. 1966.
Kusoglu A., Weber A.Z. // Chem. Rev. 2017. V. 117. P. 987.
Zhu L.Y., Li Y.C., Liu J. et al. // Pet. Sci (China). 2021. V. 19. P. 1371.
Ng W.W., Thiam H.S., Pang Y.L. et al. // Membranes (Basel). 2022. V. 12. № 5. P. 506.
Jiang B., Wu L., Yu L. et al. // J. Membr. Sci. 2016. V. 510. P. 18.
Sanginov E.A., Kayumov R.R., Shmygleva L.V. et al. // Solid State Ionics. 2017. V. 300. P. 26.
Yaroslavtsev A.B., Novikova S.A., Voropaeva D.Y. et al. // Batteries (Basel). 2022. V. 8. P. 162.
Doyle M., Lewittes M.E., Roelofs M.G. et al. // J. Phys. Chem. B. 2001. V. 105. P. 9387.
Doyle M., Lewittes M.E., Roelofs M.G. et al. // J. Membr. Sci. 2001. V. 184. P. 257.
Sachan S., Ray C.A., Perusich S.A. // Polym. Eng. Sci. 2002. V. 42. P. 1469.
Su L., Darling R.M., Gallagher K.G. et al. // J. Electrochem. Soc. 2016. V. 163. P. A5253.
Krupina A.A., Kayumov R.R., Nechaev G.V. et al. // Membranes (Basel). 2022. V. 12. № 9. P. 840.
Воропаева Д.Ю., Новикова С.А., Ярославцев А.Б. // Успехи химии. 2020. Т. 89. № 10. С. 1132.
Kulova T., Skundin A., Chekannikov A. et al. // Batteries. 2018. V. 4. № 4. P. 61.
Voropaeva D.Y., Novikova S.A., Kulova T.L. et al. // Solid State Ionics. 2018. V. 324. P. 28.
Воропаева Д.Ю., Ярославцев А.Б. // Мембраны и мембр. технологии. 2022. Т. 12. № 4. С. 315.
Карелин А.И., Каюмов Р.Р., Сангинов Е.А. и др. // Мембр. мембр. технол. 2016. Т. 6. № 4. С. 366.
Каюмов Р.Р., Шмыглева Л.В., Евщик Е.Ю. и др. // Электрохимия. 2021. Т. 57. № 8. С. 507.
Kayumov R.R., Sanginov E.A., Shmygleva L.V. et al. // J. Electrochem. Soc. 2019. V. 166. P. F3216.
Guglielmi M., Aldebert P., Pineri M. // J. Appl. Electrochem. 1989. V. 19. P. 167.
Voropaeva D.Y., Novikova S.A., Kulova T.L. et al. // Ionics. 2018. V. 24. P. 1685.
Voropaeva D., Novikova S., Xu T. et al. // J. Phys. Chem. B. 2019. V. 123. № 48. P. 10217.
Сангинов Е.А., Евщик Е.Ю., Каюмов Р.Р. и др. // Электрохимия. 2015. Т. 51. № 10. С. 1115.
Istomina A.S., Yaroslavtseva T.V., Reznitskikh O.G. et al. // Polymers (Basel). 2021. V. 13. № 7. P. 1150.
Sanginov E.A., Borisevich S.S., Kayumov R.R. et al. // Electrochim. Acta. 2021. V. 373. P. 137914.
Cai Z., Liu Y., Liu S. et al. // Energy Environ. Sci. 2012. V. 5. P. 5690.
Liu Y., Cai Z., Tan L. et al. // Ibid. P. 9007.
Cao C., Wang H., Liu W. et al. // Intern. J. Hydrogen Energy. 2014. V. 39. P. 16110.
Simari C., Tuccillo M., Brutti S. et al. // Electrochim. Acta. 2022. V. 410. P. 139936.
Резницких О.Г., Истомина А.С., Борисевич С.С. и др. // ЖФХ. 2021. Т. 95. № 6. С. 867.
Fulem M., Růžička K., Růžička M. // Fluid Phase Equilib. 2011. V. 303. № 2. P. 205.
Ahlers J., Lohmann J., Gmehling J. // J. Chem. Eng. Data. 1999. V. 44. № 4. P. 727.
Domalski E.S., Hearing E.D. // J. Phys. Chem. Ref. Data. 1990. V. 19. P. 881.
Jannelli L., Pansini M. // J. Chem. Eng. Data. 1985. V. 30. P. 428.
Feldheim D.L., Lawson D.R., Martin C.R. // J. Polym. Sci. B. 1993. V. 31. P. 953.
Thompson E.L., Capehart T.W., Fuller T.J. et al. // J. Electrochem. Soc. 2006. V. 153. P. A2351.
Lue S.J., Shieh S.J. // J. Macromol. Sci. B. 2009. V. 48. P. 114.
Смирнов В.А., Дубовицкий В.А., Денисов Н.Н. и др. // Хим. физика. 2018. Т. 37. № 6. P. 72.
Gruger A., Régis A., Schmatko T. et al. // Vib. Spectrosc. 2001. V. 26. P. 215.
Karelin A.I., Kayumov R.R., Sanginov E.A. et al. // Spectrochim. Acta, Part A. 2017. V. 178. P. 94.
Bushkova O.V., Sanginov E.A., Chernyuk S.D. et al. // Membranes and Membr. Technol. 2022. V. 4. № 6. P. 433.
Bagheri S., Monajjemi M., Ziglari A. et al. // Russ. J. Phys. Chem. B. 2021. V. 15. Suppl. 1. P. S140.
Chen Z., Shao Z., Siddiqui M.K. et al. // Russ. J. Phys. Chem. B. 2019. V. 13. P. 156.
Галашева А.Е., Рахманова О.Р., Катиг К.П. и др. // Хим. физика. 2020. Т. 39. № 11. P. 80.