Saturated vapor pressures and enthalpies of vaporization of malic acid esters

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The saturated vapor pressures of malic acid diesters and linear С1-С5 alcohols are determined using the transpiration method in the temperature range of 303–369 K. The enthalpies of vaporization of esters at 298.2 K are determined on the basis of the obtained data. Correlations of the enthalpies of vaporization from Kovats indices and number of carbon atoms are obtained. The contributions of the hydroxyl group and intermolecular hydrogen bonds to are estimated. The author’s QSPR method for calculating the values of the enthalpies of vaporization of esters of hydroxy acids is modified.

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作者简介

Yu. Yamshchikova

Samara State Technical University

Email: kinterm@samgtu.ru
俄罗斯联邦, Samara

S. Portnova

Samara State Technical University

Email: kinterm@samgtu.ru
俄罗斯联邦, Samara

E. Krasnykh

Samara State Technical University

编辑信件的主要联系方式.
Email: kinterm@samgtu.ru
俄罗斯联邦, Samara

参考

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2. Fig. 1. Structure of malic acid esters.

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3. Fig. 2. Comparison of saturated vapor pressures for dimethylmalate: • - given work; ○ - [21].

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4. Fig. 3. Comparison of saturated vapor pressures for diethylmalate: • - the present work; ○ - [21].

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5. Fig. 4. Dependences of DvapHo values (298.15 K) on the number of carbon atoms of the alcohol moiety.

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6. Fig. 5. Location of substituents relative to the -OH-group in the molecules of alkyl glycolates, alkyl lactates and dialkylmalates.

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