Electrocatalytic Reduction of CO2 when Using N-Substituted Salts of 2,4,6-Triphenylpyridine

A. V. Knyazev; Князев А. В.; A. V. Dolganov; Долганов А. В.; L. A. Klimaeva; Климаева Л. А.; S. G. Kostryukov; Кострюков С. Г.; A. Sh. Kozlov; Козлов А. Ш.; A. D. Yudina; Юдина А. Д.; O. V. Tarasova; Тарасова О. В.

doi:10.31857/S0044453723080058

Electrocatalytic Reduction of CO2 when Using N-Substituted Salts of 2,4,6-Triphenylpyridine

Authors: Knyazev A.V.¹, Dolganov A.V.², Klimaeva L.A.², Kostryukov S.G.², Kozlov A.S.², Yudina A.D.², Tarasova O.V.²
Affiliations:
1. Lobachevsky State University
2. Ogarev Mordovian State University
Issue: Vol 97, No 8 (2023)
Pages: 1097-1105
Section: ХИМИЧЕСКАЯ КИНЕТИКА И КАТАЛИЗ
Submitted: 26.02.2025
Published: 01.08.2023
URL: https://vestnikugrasu.org/0044-4537/article/view/668674
DOI: https://doi.org/10.31857/S0044453723080058
EDN: https://elibrary.ru/QTUEON
ID: 668674

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

A study is performed of the electrocatalytic activity of substituted pyridine salts (N-hydro-, N‑methyl-, and N-phenyl-2,4,6-triphenylpyridinium perchlorates) in the electroreduction of carbon dioxide to carbon monoxide. The effect the natures of the substituent and the H+ source have on the efficiency of the process is determined. The main reasons for the occurrence of the electrocatalytic process are identified, and the values of TOF (catalyst speed) and TON (number of revolutions of the catalyst) are calculated. It is shown that the values of TOF and TON fall as the pK of the acid rises.

Keywords

electrocatalyst, pyridine, reduction, carbon dioxide

References

Liu J.-L., Wang X., Li X.-S. et al. // J. Phys. D: Appl. Phys. 2020. V. 53. № 25. P. 253001.https://doi.org/10.1088/1361-6463/ab7c04
Jenkinson D.S., Adams D.E., Wild A. // Nature. 1991. V. 351. № 6324. P. 304. https://doi.org/10.1038/351304a0.
Weimer T., Schaber K., Specht M. et al. // Energy Conversion and Management/ 1996. V. 370020 № 6–8. P. 1351.https://doi.org/10.1016/0196-8904(95)00345-2
Ren S., Joulié D., Salvatore D. // Science. 2019. V. 365. № 6451. P. 367.https://doi.org/10.1126/science.aax4608
Jin S., Hao Z., Zhang K. // Angewandte Chemie. 2021. V. 133. № 38. P. 20795.https://doi.org/10.1002/ange.202101818
Nielsen D.U., Hu X.-M. // Nat. Catal. 2018. V. 1. № 4. P. 244.https://doi.org/10.1038/s41929-018-0051-3
Hori Y., Wakebe H., Tsukamoto T. et al. // Electrochimica Acta. 1994. № 39. № 11–12. P. 1833.https://doi.org/10.1016/0013-4686(94)85172-7
Gao X., Liang J., Wu L. et al. // Catalysts. 2022. V. 12. № 1. P. 66.https://doi.org/10.3390/catal12010066
Frontera P., Macario A., Ferraro M. et al. // Catalysts. 2017. V. 7. № 12. P. 59.https://doi.org/10.3390/catal7020059
Mikhail M., Wang B., Jalain R. et al. // Reac. Kinet. Mech. Cat. 2019. V. 126. № 2. P. 629–643.https://doi.org/10.1007/s11144-018-1508-8
Zhu D.D., Liu J.L., Qiao S.Z. // Adv. Mater. 2016. V. 28. № 18. P. 3423.https://doi.org/10.1002/adma.201504766
Alberico E., Nielsen M. // Chem. Commun. 2015. V. 51. № 31. P. 6714.https://doi.org/10.1039/C4CC09471A
Dong K., Razzaq R., Hu Y. // Top Curr. Chem. (Z). 2017. V. 375. № 2. P. 23.https://doi.org/10.1007/s41061-017-0107-x
Boutin E., Robert M. // Trends in Chemistry. 2021. V. 3. № 5. P. 359.https://doi.org/10.1016/j.trechm.2021.02.003
Qiao J., Liu Y., Hong F. // Chem. Soc. Rev. 2014. V. 43. № 2. P. 631.https://doi.org/10.1039/C3CS60323G
Zheng Y., Vasileff A., Zhou X. et al. // J. Am. Chem. Soc. 2019. V. 141. № 19. P. 7646.https://doi.org/10.1021/jacs.9b02124
Lim R.J., Xie M., Sk M.A. et al. // Catalysis Today. 2014. V. 233. P. 169.https://doi.org/10.1016/j.cattod.2013.11.037
Specht M. // International Journal of Hydrogen Energy. 1998. V. 23. № 5. P. 387.https://doi.org/10.1016/S0360-3199(97)00077-3
Barton Cole E., Lakkaraju P.S., Rampulla D.M. et al. // J. Am. Chem. Soc. 2010. V. 132. № 33. P. 11539.https://doi.org/0.1021/ja1023496
Dolganov A.V., Tanaseichuk B.S., Pryanichnikova M.K., et al. // J. Phys. Org. Chem. 2019. V. 32. № 5. e3930.https://doi.org/10.1002/poc.3930
Dolganov A.V., Muryumin E.E., Chernyaeva O.Y. et al. // Materials Chemistry and Physics. 2019. V. 224. P. 148.https://doi.org/10.1016/j.matchemphys.2018.12.006
Dolganov A.V., Tanaseichuk, B.S., Tsebulaeva Y.V. et al. // Int. J. Electrochem. Sci. 2016. P. 9559.https://doi.org/10.20964/2016.11.24
Dolganov A.V., Tanaseichuk B.S., Yurova V.Yu. et al. // Intern. J. of Hydrogen Energy 2019. V. 44. № 39. P. 21495.https://doi.org/10.1016/j.ijhydene.2019.06.067
Dolganov A.V., Tanaseichuk B.S., Moiseeva D.N. et al. // Electrochem. Commun., 2016. V. 68. P. 59. https://doi.org/10.1016/j.elecom.2016.04.015
Dolganov A.V., Chernyaeva O.Y., Kostryukov S.G. et al. // Intern. J. of Hydrogen Energy 2020. V. 45. № 1. P. 501.https://doi.org/10.1016/j.ijhydene.2019.10.175
Ganz O.Yu., Klimaeva L.A., Chugunov D.B. et al. // Russ. J. Phys. Chem. 2022. V. 96 № 5. P. 954.https://doi.org/10.1134/S0036024422050120
Klimaeva L.A., Ganz O.Yu., Chugunov D.B. et al. // Russ. J. Phys. Chem. 2022. V. 96. № 5. P. 958.https://doi.org/10.1134/S0036024422050156
Urban J., Volke J. // Collect. Czech. Chem. Commun. 1994. V. 59. № 11. P. 2545.https://doi.org/10.1135/cccc19942545