Effect of additive modifiers on the combustion characteristics of composite aluminized propellants

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Resumo

We studied the effect of modifier additives TiB2, AlMgB14, (NH4)2TiF6, NH4BF4, Ca3(PO4)2 on the combustion parameters of composite propellants based on aluminum powder as a fuel (about 20% wt.), ammonium perchlorate as an oxidizer (about 60% wt.), and energetic binder (MPVT about 20% wt.). Additives were introduced in an amount of about 2%. The burning rates of propellants were measured and condensed combustion products were studied at a pressure of 0.35 MPa. The effect of additives was assessed using the following parameters: increasing the burning rate, reducing combustion incompleteness, mass and size of agglomerates. The most effective additives were NH4BF4 and TiB2. Conclusions are drawn about the prospects of using the studied additives to obtain the required combustion parameters.

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Sobre autores

O. Glotov

Voevodsky Institute of Chemical Kinetics and Combustion Siberian Branch of the Russian Academy of Sciences; Novosibirsk State Technical University

Autor responsável pela correspondência
Email: glotov@kinetics.nsc.ru
Rússia, Novosibirsk; Novosibirsk

N. Belousova

Voevodsky Institute of Chemical Kinetics and Combustion Siberian Branch of the Russian Academy of Sciences; Novosibirsk State Technical University

Email: glotov@kinetics.nsc.ru
Rússia, Novosibirsk; Novosibirsk

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2. Fig. 1. Mass distribution functions of aluminum, medium and coarse ammonium perchlorate particle sizes.

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3. Fig. 2. Scheme of variation of fuel composition.

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4. Fig. 3. Photographs of the pressure vessel (minibomb) and its tooling.

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5. Fig. 4. Frames of video recording of the combustion process of the miniature sample in the minibomb for the selection of particles-products of combustion. Video shooting “by light” under illumination through the back window of the minibomb: left frame - view before combustion, right frame - in the process of combustion: 1 - sample in a Plexiglas cup fixed on a bracket; 2 - ignition wire; 3 - combustion surface. It can be seen that it has shifted from the cut of the beaker to the depth (upwards); x - one of the parasitic reflections that are formed on the faces of the beaker with freezing liquid; L - distance from the sample to the surface of the liquid before ignition of the sample.

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6. Fig. 5. Effect of modifier additives on the combustion rates of the studied fuels at a pressure of 0.35 MPa: figures 1, 2, 3 correspond to fuels of lines 1, 2, 3 (see fig. 2).

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7. Fig. 6. Variation of dimensionless mass m80 of agglomerate particles: figures 1, 2, 3 correspond to fuels of lines 1, 2, 3.

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8. Fig. 7. Effect of additives on the average size D43 of agglomerate particles: figures 1, 2, 3 correspond to fuels of lines 1, 2, 3; horizontal dashed lines 1c, 2c, 3c - calculation by the model [57] for fuels of lines 1, 2, 3.

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9. Fig. 8. Variation of incomplete combustion h depending on the type of additive: figures 1, 2, 3 correspond to fuels of lines 1, 2, 3.

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10. Fig. 9. Effect of additives on fine particle size d32: figures of curves 1, 2, 3 correspond to fuels of lines 1, 2, 3.

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